However, faced with diverse scenarios and harsh working conditions (e.g., low temperature), the successful operation of batteries suffers great challenges. At low temperature, the increased viscosity of electrolyte leads to the poor wetting of batteries and sluggish transportation of Li-ion (Li +) in bulk electrolyte.
Low temperature will reduce the overall reaction rate of the battery and cause capacity decay. These failures of batteries at low temperatures are related to the obstruction of ion transport.
Last but not the least, battery testing protocols at low temperatures must not be overlooked, taking into account the real conditions in practice where the battery, in most cases, is charged at room temperature and only discharged at low temperatures depending on the field of application.
Here, we first review the main interfacial processes in lithium-ion batteries at low temperatures, including Li + solvation or desolvation, Li + diffusion through the solid electrolyte interphase and electron transport.
Stable operation of rechargeable lithium-based batteries at low temperatures is important for cold-climate applications, but is plagued by dendritic Li plating and unstable solid–electrolyte interphase (SEI). Here, we report on high-performance Li metal batteries under low-temperature and high-rate-charging conditions.
However, commercially available lithium-ion batteries (LIBs) show significant performance degradation under low-temperature (LT) conditions. Broadening the application area of LIBs requires an improvement of their LT characteristics.