In this article, we report the addition of graphene (Gr) to negative active materials (NAM) of lead-acid batteries (LABs) for sulfation suppression and cycle-life extension. Our experimental results show that with an addition of only a fraction of a percent of Gr, the partial state of charge (PSoC) cycle life is si
However, the cycle times of lead-acid batteries are low, generally around 350 times, while the cycle times of graphene batteries are at least 3 times that of lead-acid batteries. However, the lithium metal after scrapped graphene batteries has extremely high environmental pollution and poor recyclability.
Compared with lead-acid batteries, graphene batteries are smaller in size and lighter in weight under the same power. The volume and weight of lithium batteries are one-third of that of lead-acid batteries under the same power. Restricted by technology and cost, it is currently mainly used in electric two-wheelers and mobile phones.
The arrangement structure allows electrons to pass through quickly, allowing the use of graphene batteries to have an extremely fast charging speed. As GAC advertises, electric vehicles are fully charged to 80% in 8 minutes. The activity of lead-acid batteries is lower than that of lithium batteries.
When this material is employed as the negative additive, the HRPSoC cycle life of lead-acid battery is tremendously prolonged by more than 224% from 8142 cycles to 26,425 cycles, which is also higher than that of the other two carbon additives.
The test results show that the low-temperature performance, charge acceptance, and large-current discharge performance of the batteries with graphene additives were significantly improved compared to the control battery, and the cycle life under 100% depth of discharge condition was extended by more than 52% from 250 to 380 cycles.