Most lead-acid batteries are constructed with the positive electrode (the anode) made from a lead-antimony alloy with lead (IV) oxide pressed into it, although batteries designed for maximum life use a lead-calcium alloy. The negative electrode (the cathode) is made from pure lead and both electrodes are immersed in sulphuric acid.
The lead acid battery uses lead as the anode and lead dioxide as the cathode, with an acid electrolyte. The following half-cell reactions take place inside the cell during discharge: At the anode: Pb + HSO4– → PbSO4 + H+ + 2e– At the cathode: PbO2 + 3H+ + HSO4– + 2e– → PbSO4 + 2H2O Overall: Pb + PbO2 +2H2SO4 → 2PbSO4 + 2H2O
A lead-acid battery cell consists of a positive electrode made of lead dioxide (PbO 2) and a negative electrode made of porous metallic lead (Pb), both of which are immersed in a sulfuric acid (H 2 SO 4) water solution. This solution forms an electrolyte with free (H+ and SO42-) ions. Chemical reactions take place at the electrodes:
Specifically, a novel characteristic distribution model is proposed to determine the grouping priority of different batteries. Then, an improved k-nearest-neighbor algorithm is used to decide which batteries should be group into the same battery pack. Experimental results demonstrate the effectiveness of the proposed method.
Lead-acid batteries can be dangerous because they vent hydrogen and oxygen gas during operation. The following points should be remembered: Keep the electrolyte in flooded cells at the correct level with distilled water, to make good losses due to evaporation and gassing.
The capacities of lead-acid batteries are very dependent on the temperature at which the battery is operating. The Capacity is normally quoted for a temperature of 25°C however, the capacity will reduce by about 50% at -25°C and will increase to about 10% at 45°C (figure 5).