Third-generation photovoltaic cells are solar cells that are potentially able to overcome the Shockley–Queisser limit of 31–41% power efficiency for single bandgap solar cells. This includes a range of alternatives to cells made of semiconducting p-n junctions ("first generation") and thin film cells ("second generation").
This review focuses on different types of third-generation solar cells such as dye-sensitized solar cells, Perovskite-based cells, organic photovoltaics, quantum dot solar cells, and tandem solar cells, a stacked form of different materials utilizing a maximum solar spectrum to achieve high power conversion efficiency.
Modified third-generation solar cells, for example, tandem and/or organic–inorganic configurations, are emerging as fourth-generation solar cells to maximize their economic efficiency. This chapter comprehensively covers the basic concepts, performance, and challenges associated with third-generation solar cells.
(3) Third generation, which are semiconducting-based solution-processed PV technologies [8, 9]. According to Green , third-generation solar cells are defined as those capable of high power-conversion efficiency while maintaining a low cost of production.
The high cost of materials processing and complicated fabrication methodologies of the first generation of solar cells, and the fluctuation in device performance of second-generation solar cells, motivated the development of a third generation of solar cells with viable technology for large-scale photovoltaics to reach the terawatt scale.
Third-generation PVs are of interest due to their flexible fabrication process, light weight, low cost, and high efficiencies. Key characteristics of third-generation solar cells are high-power conversion efficiency (PCE) > SQ and low cost per unit area.