The thermal safety performance of lithium-ion batteries is significantly affected by high-temperature conditions. This work deeply investigates the evolution and degradation mechanism of thermal safety for lithium-ion batteries during the nonlinear aging process at high temperature.
As rechargeable batteries, lithium-ion batteries serve as power sources in various application systems. Temperature, as a critical factor, significantly impacts on the performance of lithium-ion batteries and also limits the application of lithium-ion batteries. Moreover, different temperature conditions result in different adverse effects.
Roder , Xia , Hildebrand , Waldmann , Cai et al. reported that thermal stability of lithium-ion batteries declined after high-temperature aging, evidenced by a decrease in the onset self-heating temperature and an increase in self-heating rate. However, some researchers have reached contrasting conclusions.
Lithium-ion batteries, the predominant energy storage technology, are increasingly challenged to function across a broad thermal spectrum. As essential carriers for ion transport, electrolytes necessitate adaptability to these extensive temperature variations.
However, the thermal stability of lithium-ion batteries has experienced a significant decline due to the intensified energy density , , leading to a higher frequency and severity of battery safety accidents.
(27) Abda found that the onset self-heating temperature increased while the thermal runaway triggering temperature decreased after high-temperature aging for lithium iron phosphate batteries. (28) Larsson found that the thermal stability of lithium cobalt oxide batteries would not change significantly after high-temperature aging.