In this article, we report the addition of graphene (Gr) to negative active materials (NAM) of lead-acid batteries (LABs) for sulfation suppression and cycle-life extension. Our experimental results show that with an addition of only a fraction of a percent of Gr, the partial state of charge (PSoC) cycle life is si
This research enhances the capacity of the lead acid battery cathode (positive active materials) by using graphene nano-sheets with varying degrees of oxygen groups and conductivity, while establishing the local mechanisms involved at the active material interface.
(5) and (6) showed the reaction of lead-acid battery with and without the graphene additives. The presence of graphene reduced activation energy for the formation of lead complexes at charge and discharge by providing active sites for conduction and desorption of ions within the lead salt aggregate.
The work done by Witantyo et al. on applying graphene materials as additives in lead-acid battery electrodes obtained that the additive increases the conductance and enhanced battery performance . Dong and the group checked the performance of multi-walled carbon nanotubes (a-MWCNTs) as an additive for the lead acid battery. ... ...
When used as a composite in electrodes, graphene facilitates fast charging as a result of its high conductivity and well-ordered structure. Graphene has been also applied to Li-ion batteries by developing graphene-enabled nanostructured-silicon anodes that enable silicon to survive more cycles and still store more energy.
The plethora of OH bonds on the graphene oxide sheets at hydroxyl, carboxyl sites and bond-opening on epoxide facilitate conduction of lead ligands, sulphites, and other ions through chemical substitution and replacements of the −OH. Eqs. (5) and (6) showed the reaction of lead-acid battery with and without the graphene additives.